I have successfully added support for the PS3 Bluetooth Remote and the Nintendo Wii Remote or Wiimote which is also Bluetooth. So if anyone wants to control VLC or any other Windows application with one of those remotes they can. Not sure why you would want to use the Wiimote but someone out there might.
BETA is available on our download page: http://melloware.com/download/
Instructions for pairing your Bluetooth remote to your PC and getting it to work with Intelliremote is in the User Manual PDF which is included in the install.