Postby randcraw » 13 Jul 2015 23:00
The following works for me on a Mac 10.9.5 and VLC 2.2.1:
1) Delete the file ~/Library/Application Support/org.videolan.vlc/ml.xspf
This contains the list of all your songs. If you don't want to leap without a net, then just rename the file so you can restore it later.
2) Reload your iTunes library using "File -> Open File". Then browse to your iTunes folder that ends in ".../iTunes Media/Music". This is the parent folder that contains all the folders named for your album artists. Then click on Open.
That will reload your iTunes directory tree and any updates, and recreate ml.xspf.