If by "proper look" you mean opening it in a plist editor AND a text editor, that's exactly what I did.
When opened in a plist editor, the file names fall under recentlyPlayedMedia and recentlyPlayedMediaList.
I securely erased it last night, so it's gone now.
I just looked at the new file that was created after rebooting and playing one video last night. It contains the name of that one file even though
recent files was cleared.
So again I say, THAT IS A SECURITY RISK!
Anyone looking in that file can see what's been played.
VLC should
NOT keep a running record of played files after
recent files has been cleared.
There are a few items in the plist for things like window size and whether auto-updates are enabled.
But as I said, most settings are in the vlcrc file.
###
### vlc 2.2.4
###
###
### lines beginning with a '#' character are comments
###
[zvbi] # VBI and Teletext decoder
# Teletext page (integer)
#vbi-page=100
# Teletext transparency (boolean)
#vbi-opaque=0
# Teletext alignment (integer)
#vbi-position=8
# Teletext text subtitles (boolean)
#vbi-text=0
[yuv] # YUV video output
# device, fifo or filename (string)
#yuv-file=stream.yuv
# Chroma used (string)
#yuv-chroma=
# YUV4MPEG2 header (default disabled) (boolean)
#yuv-yuv4mpeg2=0
[x264] # H.264/MPEG-4 Part 10/AVC encoder (x264)
# Maximum GOP size (integer)
#sout-x264-keyint=250
# Minimum GOP size (integer)
#sout-x264-min-keyint=25
# Use recovery points to close GOPs (boolean)
#sout-x264-opengop=0
# Enable compatibility hacks for Blu-ray support (boolean)
#sout-x264-bluray-compat=0
# Extra I-frames aggressivity (integer)
#sout-x264-scenecut=40
# B-frames between I and P (integer)
#sout-x264-bframes=3
# Adaptive B-frame decision (integer)
#sout-x264-b-adapt=1
# Influence (bias) B-frames usage (integer)
#sout-x264-b-bias=0
# Keep some B-frames as references (string)
#sout-x264-bpyramid=normal
# CABAC (boolean)
#sout-x264-cabac=1
# Use fullrange instead of TV colorrange (boolean)
#sout-x264-fullrange=0
# Number of reference frames (integer)
#sout-x264-ref=3
# Skip loop filter (boolean)
#sout-x264-nf=0
# Loop filter AlphaC0 and Beta parameters alpha:beta (string)
#sout-x264-deblock=0:0
# Strength of psychovisual optimization, default is "1.0:0.0" (string)
#sout-x264-psy-rd=1.0:0.0
# Use Psy-optimizations (boolean)
#sout-x264-psy=1
# H.264 level (string)
#sout-x264-level=0
# H.264 profile (string)
#sout-x264-profile=high
Etc.
Etc.
Etc.